Ionic fluids: charge and density correlations near gas-liquid criticality.

نویسندگان

  • Oksana Patsahan
  • Ihor Mryglod
  • Jean-Michel Caillol
چکیده

The correlation functions of an ionic fluid with charge and size asymmetry are studied within the framework of the random phase approximation. The results obtained for the charge-charge correlation function demonstrate that the second-moment Stillinger-Lovett (SL) rule is satisfied away from the gas-liquid critical point (CP) but not, in general, at the CP. However, in the special case of a model without size asymmetry the SL rules are satisfied even at the CP. The expressions for the density-density and charge-density correlation functions valid far from and close to the CP are obtained explicitly.

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عنوان ژورنال:
  • Journal of physics. Condensed matter : an Institute of Physics journal

دوره 17 25  شماره 

صفحات  -

تاریخ انتشار 2005